Hi,
For XMI, there are some features (http://plantuml.sourceforge.net/xmi.html) but I don't think it will help you.
You probably have to parse the SVG generated by PlantUML to show additional information, but this is not easy to do.
About mouseover feature, we are thinking about allowing this:
class Example
mouseover Example {
mouseover
--
Dummy text
}
Current version of PlantUML recognizes the syntax, but drawing is not really implemented, and is supposed to work only for SVG. Is it what you are looking for ?